Angelina Jolie, Brad Pitt Enchant at 64th Annual Cannes Film Festival

Angelina Jolie looked resplendent in a chocolate Atelier Versace strapless silk gown walking the red carpet with partner Brad Pitt for the premiere of his The Tree of Life on Monday, May 16 in France.

The 35-year-old hot mama-of-six opted for a voluminous gown with a long train and a thigh high slit on the left leg, starting just below a chunky bow on low waist.

She showed her long well toned leg through the slit while walking and posing for photogs.

She accessorized with matching Ferragamo peep toe heels and a bangle and stud earrings from her own collection with Robert Procop.

Her brunette hair, styled in soft waves with a side parting, draped her right shoulder. She wore brown eyeshadow, thick eyeliner on lids and cat eyeliner on lower lashes. Nude lip gloss rounded her exquisite looks.

Brad, 47, looked dapper in a Tom Ford shawl lapel tuxedo accented with cuff links, black dress shoes, tinted glasses and slicked back hair. He sported a goatee with just strands of grey for the perfect young and distinguished look.

Earlier in the day, Brad stepped out in all white accompanied by his 30-year-old co-star, Jessica Chastain, for a photo call to plug the film, in which she plays his wife.

Other celebrities attending the film's official premiere included cast members Jessica Chastain, Sean Penn - who plays Pitt's son, Henry Hopper and Mia Wasikowska; Gavin Rossdale and Gwen Stefani, Rob Lowe, Zoe Saldana and French actress Elsa Zylberstein.